Functionalized templates for the convergent assembly of polyethers: Synthesis of HIJK rings of gymnocin A

Aaron R. Van Dyke; T. F. Jamison; Aaron R. VanDyke

doi:10.1002/anie.200900924

Functionalized templates for the convergent assembly of polyethers: Synthesis of HIJK rings of gymnocin A

Aaron R. Van Dyke, T. F. Jamison, Aaron R. VanDyke

Fairfield University

Fairfield University

Research output: Contribution to journal › Article › peer-review

Abstract

<p> The successful application of epoxide-opening strategies towards the synthesis of ladder-type polyethers is contingent upon further elaboration of the product. By employing two different functionalized templates, a fragment of gymnocin&emsp14;A that bears four sites for subsequent fragment coupling has been prepared (see scheme; Bn=benzyl).</p>

Original language	American English
Journal	Angewandte Chemie International Edition
Volume	48
DOIs	https://doi.org/10.1002/anie.200900924
State	Published - Jan 1 2009

Keywords

cascade reactions
metathesis
natural products
polyethers
template synthesis

Disciplines

Chemistry
Physical Sciences and Mathematics

Access to Document

10.1002/anie.200900924License: CC BY

Cite this

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title = "Functionalized templates for the convergent assembly of polyethers: Synthesis of HIJK rings of gymnocin A",

abstract = " The successful application of epoxide-opening strategies towards the synthesis of ladder-type polyethers is contingent upon further elaboration of the product. By employing two different functionalized templates, a fragment of gymnocin\&emsp14;A that bears four sites for subsequent fragment coupling has been prepared (see scheme; Bn=benzyl).",

keywords = "cascade reactions, metathesis, natural products, polyethers, template synthesis",

author = "\{Van Dyke\}, \{Aaron R.\} and Jamison, \{T. F.\} and VanDyke, \{Aaron R.\}",

year = "2009",

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doi = "10.1002/anie.200900924",

language = "American English",

volume = "48",

journal = "Angewandte Chemie International Edition",

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AU - Jamison, T. F.

AU - VanDyke, Aaron R.

PY - 2009/1/1

Y1 - 2009/1/1

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AB - The successful application of epoxide-opening strategies towards the synthesis of ladder-type polyethers is contingent upon further elaboration of the product. By employing two different functionalized templates, a fragment of gymnocin&emsp14;A that bears four sites for subsequent fragment coupling has been prepared (see scheme; Bn=benzyl).

KW - cascade reactions

KW - metathesis

KW - natural products

KW - polyethers

KW - template synthesis

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ER -

Functionalized templates for the convergent assembly of polyethers: Synthesis of HIJK rings of gymnocin A

Abstract

Keywords

Disciplines

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